Chemical Equilibrium

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This topic covers the concept of chemical equilibrium, including Le Chatelier’s principle, equilibrium constants, and acid-base and solubility equilibrium.

Reaction Quotient (Qc/Qp): The ratio of concentrations of products to reactants at any point in reaction, which helps determine whether the reaction has reached equilibrium or not.
Equilibrium Constant (Kc/Kp): The ratio of concentrations/pressures of products to reactants at equilibrium, which varies with temperature and is a measure of how far the reaction proceeds to the right.
Le Chatelier's Principle: A principle that states that when a system in equilibrium is subjected to a stress, it will shift position to counteract the stress and re-establish equilibrium.
Factors Affecting Equilibrium: Factors such as temperature, pressure, and concentration that affect the position of the equilibrium and determine the rate of reaction.
Acid-Base Equilibria: Equilibria involving the transfer of protons between species in solution, characterized by the acid dissociation constant, Ka, and the base dissociation constant, Kb.
Solubility Equilibria: Equilibria involving the dissolution of sparingly soluble salts in water, characterized by the solubility product constant, Ksp.
Equilibrium Calculations: The application of equilibrium concepts and equations to calculate the concentrations of reactants and products at equilibrium, and to predict the direction of the reaction.
Heterogeneous Equilibria: Equilibria involving reactants and/or products in different physical states, such as gases, liquids, and solids.
The Law of Mass Action: A law that states that the rate of a chemical reaction is proportional to the product of the concentrations/pressures of the reactants, each raised to a power equal to its stoichiometric coefficient.
Equilibrium Expressions: Mathematical expressions that describe the equilibrium concentrations/pressures of reactants and products in terms of the equilibrium constant and initial concentrations/pressures.
- "Chemical equilibrium is the state in which both the reactants and products are present in concentrations which have no further tendency to change with time."
- "This state results when the forward reaction proceeds at the same rate as the reverse reaction."
- "The reaction rates of the forward and backward reactions are generally not zero."
- "They are equal."
- "There are no net changes in the concentrations of the reactants and products."
- "Such a state is known as dynamic equilibrium."
- "There is no observable change in the properties of the system."
- "Both the reactants and products are present in concentrations which have no further tendency to change with time."
- "The forward reaction proceeds at the same rate as the reverse reaction."
- "There are no net changes in the concentrations of the reactants and products."
- No direct quote in the paragraph, but can be inferred as a characteristic of chemical processes.
- "There is no observable change in the properties of the system."
- "Such a state is known as dynamic equilibrium."
- "Both the reactants and products are present in concentrations which have no further tendency to change with time."
- "The forward reaction proceeds at the same rate as the reverse reaction."
- "Both the reactants and products are present in concentrations which have no further tendency to change with time."
- "Both the reactants and products are present in concentrations which have no further tendency to change with time."
- No direct quote in the paragraph about the consequences, but it would indicate the system is not at equilibrium.
- "Both the reactants and products are present in concentrations which have no further tendency to change with time."
- "Both the reactants and products are present in concentrations which have no further tendency to change with time."