Quote: "Organometallic chemistry is the study of organometallic compounds, chemical compounds containing at least one chemical bond between a carbon atom of an organic molecule and a metal."
The study of chemical compounds containing bonds between carbon and a metal.
Structure and Bonding: The study of the electronic structure of organometallic molecules and the interaction between metals and organic ligands.
Spectroscopic Methods: Techniques like Nuclear Magnetic Resonance (NMR) and Infrared Spectroscopy (IR) used to identify and characterize organometallic compounds.
Reactions and Mechanisms: The study of the chemical transformations that occur in organometallic compounds and the mechanisms by which they occur.
Ligands and Coordination Chemistry: The types of ligands that can form complexes with metals and how they interact with metals in organometallic compounds.
Synthesis and Catalysis: The development of new synthetic methods for organometallic compounds and the use of organometallic compounds as catalysts in organic reactions.
Organometallic Reagents: The study of organometallic compounds as powerful reagents in organic synthesis, including Grignard reagents and organolithium reagents.
Organometallic Main Group Compounds: The study of organometallic compounds containing main group elements, such as boron, silicon, and phosphorus.
Organometallic Transition Metal compounds: The study of organometallic compounds containing transition metals, including iron, palladium, and platinum.
Applications in Industry: The use of organometallic chemistry in various industries, ranging from pharmaceuticals to electronics.
Emerging Topics: The study of new developments in organometallic chemistry, including research on carbon-carbon bond formation, metal-organic frameworks, and nanomaterials.
Synthesis of Organometallic Compounds: The synthesis of organometallic compounds involves the creation of carbon-metal bonds. This can be achieved through a variety of reactions, including direct metal insertion, oxidative addition, and transmetalation.
Catalysis: Organometallic compounds are widely used as catalysts in both homogeneous and heterogeneous reactions. Homogeneous catalysis involves the use of a soluble organometallic compound to accelerate a reaction, while heterogeneous catalysis utilizes organometallic compounds supported on a surface.
Ligand Design: Ligands are molecules that bind to metal ions to create coordination compounds. Organometallic chemistry is used to design and synthesize new ligands with specific properties, such as selective binding to certain metal ions or enhanced catalytic activity.
Bioorganometallic chemistry: Bioorganometallic chemistry explores the interactions between organometallic compounds and biological systems. This includes the development of metal-based drugs, the study of metalloproteins, and the application of metalloenzymes in biocatalysis.
Materials Science: Organometallic chemistry contributes to materials science by providing new synthetic routes for the production of advanced materials, such as polymers, nanoparticles, and thin films.
Organometallic Electronic Materials: Organometallic compounds are used in the fabrication of electronic devices, including organic light-emitting diodes (OLEDs), solar cells, and field-effect transistors.
Organometallic Organizers: Organometallic organizers are used to create ordered structures in self-assembly processes. This technique involves the use of metal ions to control the arrangement of organic molecules in the formation of supramolecular structures.
Organometallic Catalytic Conversion of Biomass: Biomass is a promising source of sustainable energy and organic chemicals. Organometallic chemistry is used in the development of catalysts for the conversion of biomass into useful products, such as biofuels and biochemicals.
Industrial Processes: Industrial processes, such as petroleum refining and polymer production, rely heavily on organometallic chemistry. Organometallic compounds are used to catalyze these reactions and to synthesize the starting materials required for these processes.
Computational Organometallic Chemistry: Computational methods are used to study the properties and reactivity of organometallic compounds. This includes the use of quantum mechanics to study electronic structure and the application of molecular dynamics simulations to simulate the behavior of molecules in solution.
Quote: "Including alkali, alkaline earth, and transition metals."
Quote: "Sometimes broadened to include metalloids like boron, silicon, and selenium."
Quote: "Bonds to 'inorganic' carbon, like carbon monoxide (metal carbonyls), cyanide, or carbide, are generally considered to be organometallic as well."
Quote: "Transition metal hydrides...are often included in discussions of organometallic compounds."
Quote: "Metal phosphine complexes are often included in discussions of organometallic compounds."
Quote: "The related but distinct term 'metalorganic compound' refers to metal-containing compounds lacking direct metal-carbon bonds but which contain organic ligands."
Quote: "Metal β-diketonates, alkoxides, dialkylamides, and metal phosphine complexes are representative members of this class."
Quote: "The field of organometallic chemistry combines aspects of traditional inorganic and organic chemistry."
Quote: "Organometallic compounds are widely used both stoichiometrically in research and industrial chemical reactions."
Quote: "In the role of catalysts to increase the rates of such reactions (e.g., as in uses of homogeneous catalysis)."
Quote: "Where target molecules include polymers, pharmaceuticals, and many other types of practical products."
Quote: "Chemical compounds containing at least one chemical bond between a carbon atom of an organic molecule and a metal."
Quote: "Sometimes broadened to include metalloids like boron, silicon, and selenium."
Quote: "Bonds to 'inorganic' carbon, like carbon monoxide (metal carbonyls), cyanide, or carbide, are generally considered to be organometallic as well."
Quote: "The related but distinct term 'metalorganic compound' refers to metal-containing compounds lacking direct metal-carbon bonds but which contain organic ligands."
Quote: "Metal β-diketonates, alkoxides, dialkylamides, and metal phosphine complexes are representative members of this class."
Quote: "The field of organometallic chemistry combines aspects of traditional inorganic and organic chemistry."
Quote: "Widely used both stoichiometrically in research and industrial chemical reactions."
Quote: "To increase the rates of such reactions (e.g., as in uses of homogeneous catalysis) where target molecules include polymers, pharmaceuticals, and many other types of practical products."